crystal structure of 1-(4-methoxyphenyl)-4-(4-nitrophenyl)-3-phenoxyazetidin-2-one

Clicks: 198
ID: 230485
2015
In the title compound, C22H18N2O5, the central β-lactam ring (r.m.s. deviation = 0.002 Å) makes dihedral angles of 64.21 (14), 82.35 (12) and 20.66 (13)° with the phenyl ring and the nitro- and methoxybenzene rings, respectively. The molecular structure is stabilized by an intramolecular C—H...O hydrogen bond. In the crystal, molecules are linked via C—H...O hydrogen bonds, forming slabs lying parallel to (111). The slabs are linked via C—H...π interactions, forming a three-dimensional network.
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Authors ;Sevim Türktekin Çelikesir;Mehmet Akkurt;Aliasghar Jarrahpour;Habib Allah Shafie;Ömer Çelik
Journal Disability and rehabilitation
Year 2015
DOI 10.1107/S2056989014025833
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989014025833
Keywords
1 crystal structure antibiotics hydrogen bonds n-heterocyclic carbenes π interactionschemistry o hydrogen bonds aromatic π–π stacking interactionschemistry

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