Structurally Isomerized Bis-Biphenyl Moieties Embedded in Hexaphyrin(3.1.1.3.1.1) and Octaphyrin(1.1.1.0.1.1.1.0).
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ID: 80650
2020
An --biphenyl moiety-incorporated 32π hexaphyrin(3.1.1.3.1.1) is successfully achieved. Replacing with connectivity in the biphenyl unit of hexaphyrin leads to the formation of its structural isomer, octaphyrin(1.1.1.0.1.1.1.0). Spectral and structural analyses reveal the lack of planarity in hexaphyrin and the presence of an -arene unit in octaphyrin, thus affording nonaromatic characteristics.
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chitranshi2020structurallyorganic
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| Authors | Chitranshi, Sangya;Das, Mainak;Adinarayana, B;Cha, Won-Young;Kim, Dongho;Srinivasan, A; |
| Journal | Organic letters |
| Year | 2020 |
| DOI | 10.1021/acs.orglett.9b04614 |
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